Phosphorescence

Phosphorescence is a type of photoluminescence where a material absorbs energy from a light source (like sunlight or UV light) and then emits light at a slower rate, even after the light source has been removed. The emitted light often has a longer wavelength than the absorbed light, causing a characteristic glow-in-the-dark effect.

Here is a short explanation of phosphorescence:

  • Excitation: When a phosphorescent material is exposed to light, electrons within the material absorb the photons’ energy and move to a higher energy state (become excited).
  • Trapped State: Unlike fluorescence, where electrons immediately return to their ground state and emit light, in phosphorescence, the excited electrons get “trapped” in a forbidden triplet state. This means they can’t directly transition back to their lower energy state.
  • Gradual Release: Over time, the trapped electrons slowly find their way back to the ground state, releasing the stored energy as light. This process is much slower than fluorescence, which is why phosphorescence produces that lingering afterglow.

Key Points:

  • Duration: Phosphorescence can last for seconds, minutes, or even hours, unlike fluorescence which ends almost immediately after the light source is removed.
  • Excitation Source: Phosphorescent materials typically need light with shorter wavelengths for excitation, such as ultraviolet light.

Examples:

  • Glow-in-the-dark toys: These are coated with phosphorescent materials.
  • Safety signs: Phosphorescent signs stay visible in low light conditions.
  • Watch dials: Some watch dials used to use phosphorescent paint for nighttime visibility (this has been replaced by safer alternatives in modern watches).
Light sources
Emission mechanism DescriptionExamples
LIGHT-EMITTING PROCESS
LuminescenceLight emission due to the excitation of electrons in a material.Electrons within a material gain energy and then release light as they return to a lower energy state.Bioelectroluminescence
Electroluminescence
Photoluminescence
- Fluorescence
- Phosphorescence
Sonoluminescence
Thermoluminescence
Blackbody radiation (Type of thermal radiation)Electromagnetic radiation (including visible light) emitted by any object with a temperature above absolute zero.Electromagnetic radiation (including visible light) emitted by any object with a temperature above absolute zero.All objects above temperature of absolute zero.
ChemiluminescenceLight from natural and artificial chemical reactions.Light from natural and artificial chemical reactions.Bioluminescence
Chemiluminescent reactions:
- Luminol reactions
- Ruthenium chemiluminescence
Nuclear reactionLight emission as a byproduct of nuclear reactions (fusion or fission).Light emitted as a byproduct of nuclear reactions.Nuclear reactors
Stars undergoing fusion
Thermal radiationLight emission due to the thermal excitation of atoms and molecules at high temperatures.Light emission due to the thermal excitation of atoms and molecules.Sun
Stars
Incandescent light bulbs
TriboluminescenceLight emission due to mechanical stress applied to a material.Light emission due to the mechanical stress applied to a material, causing the movement of electric charges and subsequent light emission.Sugar crystals cracking
Adhesive tape peeling
Quartz crystals fracturing.
Natural light source
Fireflies
Deep-sea creatures
Glowing mushrooms
Bioluminescence Light emission from biological organisms.Involves the luciferase enzyme.
Sun
Stars
Nuclear FusionLight emission as a byproduct of nuclear fusion reactions in stars.Electromagnetic spectrum (visible light, infrared, ultraviolet).
Fire
Candles
Thermal radiationLight emission due to the thermal excitation of atoms and molecules during the combustion of a fuel source.Burning of a fuel source, releasing heat and light.
Artificial light source
Fluorescent lights Highlighters
Safety vests
Chemiluminescence Light emission from chemical reactions.Fluorescence (absorption and re-emission of light).
Glow sticks
Emergency signs
ChemiluminescenceLight emission due to phosphorescence - a type of chemiluminescence.A type of chemiluminescence where light emission is delayed after the initial excitation.
Glow sticks
Light sticks
Chemiluminescence Chemiluminescence Light emission from a chemical reaction that does not involve combustion.
Tungsten light bulbs
Toasters
Thermal radiationHeated filament radiates light and heat.Light emission from a hot filament.
Fluorescent lamps
LED lights
ElectroluminescenceExcitation of atoms by electric current.Light emission when electric current excites atoms in a material.
Neon signsElectrical DischargeDischarge of electricity through gas.Light emission when electricity flows through a gas.
Sugar crystals cracking
Pressure-sensitive adhesives
TriboluminescenceLight emission from friction or pressure.Light emission due to mechanical forces.
Fluorescent paint Highlighters
Safety vests
PhotoluminescenceAbsorption and subsequent re-emission of light at a lower energy.Absorption and re-emission of light.

Light Sources: Mechanism, examples, and everyday applications

Footnote: Cerenkov radiation and Synchrotron radiation are not included in the table because they are not conventionally classified as light sources.