Phosphorescence is a type of photoluminescence where a material absorbs energy from a light source (like sunlight or UV light) and then emits light at a slower rate, even after the light source has been removed. The emitted light often has a longer wavelength than the absorbed light, causing a characteristic glow-in-the-dark effect.
Here is a short explanation of phosphorescence:
- Excitation: When a phosphorescent material is exposed to light, electrons within the material absorb the photons’ energy and move to a higher energy state (become excited).
- Trapped State: Unlike fluorescence, where electrons immediately return to their ground state and emit light, in phosphorescence, the excited electrons get “trapped” in a forbidden triplet state. This means they can’t directly transition back to their lower energy state.
- Gradual Release: Over time, the trapped electrons slowly find their way back to the ground state, releasing the stored energy as light. This process is much slower than fluorescence, which is why phosphorescence produces that lingering afterglow.
Key Points:
- Duration: Phosphorescence can last for seconds, minutes, or even hours, unlike fluorescence which ends almost immediately after the light source is removed.
- Excitation Source: Phosphorescent materials typically need light with shorter wavelengths for excitation, such as ultraviolet light.
Examples:
- Glow-in-the-dark toys: These are coated with phosphorescent materials.
- Safety signs: Phosphorescent signs stay visible in low light conditions.
- Watch dials: Some watch dials used to use phosphorescent paint for nighttime visibility (this has been replaced by safer alternatives in modern watches).
| Light sources | Emission mechanism | Description | Examples |
|---|---|---|---|
| LIGHT-EMITTING PROCESS | |||
| Luminescence | Light emission due to the excitation of electrons in a material. | Electrons within a material gain energy and then release light as they return to a lower energy state. | Bioelectroluminescence Electroluminescence Photoluminescence - Fluorescence - Phosphorescence Sonoluminescence Thermoluminescence |
| Blackbody radiation (Type of thermal radiation) | Electromagnetic radiation (including visible light) emitted by any object with a temperature above absolute zero. | Electromagnetic radiation (including visible light) emitted by any object with a temperature above absolute zero. | All objects above temperature of absolute zero. |
| Chemiluminescence | Light from natural and artificial chemical reactions. | Light from natural and artificial chemical reactions. | Bioluminescence Chemiluminescent reactions: - Luminol reactions - Ruthenium chemiluminescence |
| Nuclear reaction | Light emission as a byproduct of nuclear reactions (fusion or fission). | Light emitted as a byproduct of nuclear reactions. | Nuclear reactors Stars undergoing fusion |
| Thermal radiation | Light emission due to the thermal excitation of atoms and molecules at high temperatures. | Light emission due to the thermal excitation of atoms and molecules. | Sun Stars Incandescent light bulbs |
| Triboluminescence | Light emission due to mechanical stress applied to a material. | Light emission due to the mechanical stress applied to a material, causing the movement of electric charges and subsequent light emission. | Sugar crystals cracking Adhesive tape peeling Quartz crystals fracturing. |
| Natural light source | |||
| Fireflies Deep-sea creatures Glowing mushrooms | Bioluminescence | Light emission from biological organisms. | Involves the luciferase enzyme. |
| Sun Stars | Nuclear Fusion | Light emission as a byproduct of nuclear fusion reactions in stars. | Electromagnetic spectrum (visible light, infrared, ultraviolet). |
| Fire Candles | Thermal radiation | Light emission due to the thermal excitation of atoms and molecules during the combustion of a fuel source. | Burning of a fuel source, releasing heat and light. |
| Artificial light source | |||
| Fluorescent lights Highlighters Safety vests | Chemiluminescence | Light emission from chemical reactions. | Fluorescence (absorption and re-emission of light). |
| Glow sticks Emergency signs | Chemiluminescence | Light emission due to phosphorescence - a type of chemiluminescence. | A type of chemiluminescence where light emission is delayed after the initial excitation. |
| Glow sticks Light sticks | Chemiluminescence | Chemiluminescence | Light emission from a chemical reaction that does not involve combustion. |
| Tungsten light bulbs Toasters | Thermal radiation | Heated filament radiates light and heat. | Light emission from a hot filament. |
| Fluorescent lamps LED lights | Electroluminescence | Excitation of atoms by electric current. | Light emission when electric current excites atoms in a material. |
| Neon signs | Electrical Discharge | Discharge of electricity through gas. | Light emission when electricity flows through a gas. |
| Sugar crystals cracking Pressure-sensitive adhesives | Triboluminescence | Light emission from friction or pressure. | Light emission due to mechanical forces. |
| Fluorescent paint Highlighters Safety vests | Photoluminescence | Absorption and subsequent re-emission of light at a lower energy. | Absorption and re-emission of light. |
Light Sources: Mechanism, examples, and everyday applications
Footnote: Cerenkov radiation and Synchrotron radiation are not included in the table because they are not conventionally classified as light sources.